diff --git a/pep_sphinx_extensions/pep_zero_generator/pep_index_generator.py b/pep_sphinx_extensions/pep_zero_generator/pep_index_generator.py
index 6b5d56a4392..ac3e51e9ff4 100644
--- a/pep_sphinx_extensions/pep_zero_generator/pep_index_generator.py
+++ b/pep_sphinx_extensions/pep_zero_generator/pep_index_generator.py
@@ -63,10 +63,21 @@ def write_peps_json(peps: list[parser.PEP], path: Path) -> None:
 def create_pep_zero(app: Sphinx, env: BuildEnvironment, docnames: list[str]) -> None:
     peps = _parse_peps(Path(app.srcdir))
 
-    numerical_index_text = writer.PEPZeroWriter().write_numerical_index(peps)
+    release_peps = {
+        pep.python_version: pep.number
+        for pep in peps
+        if pep.python_version
+        and "release" in pep.topic
+    }
+
+    numerical_index_text = writer.PEPZeroWriter(
+        release_peps
+    ).write_numerical_index(peps)
     subindices.update_sphinx("numerical", numerical_index_text, docnames, env)
 
-    pep0_text = writer.PEPZeroWriter().write_pep0(peps, builder=env.settings["builder"])
+    pep0_text = writer.PEPZeroWriter(
+        release_peps
+    ).write_pep0(peps, builder=env.settings["builder"])
     pep0_path = subindices.update_sphinx("pep-0000", pep0_text, docnames, env)
     peps.append(parser.PEP(pep0_path))
 
diff --git a/pep_sphinx_extensions/pep_zero_generator/writer.py b/pep_sphinx_extensions/pep_zero_generator/writer.py
index c00860c7a8c..8289474c161 100644
--- a/pep_sphinx_extensions/pep_zero_generator/writer.py
+++ b/pep_sphinx_extensions/pep_zero_generator/writer.py
@@ -59,8 +59,9 @@ class PEPZeroWriter:
         801: "Warsaw",
     }
 
-    def __init__(self):
+    def __init__(self, release_peps: dict[str, int] | None = None):
         self.output: list[str] = []
+        self.release_peps = release_peps or {}
 
     def emit_text(self, content: str) -> None:
         # Appends content argument to the output list
@@ -87,7 +88,14 @@ def emit_pep_row(
         self.emit_text(f"     - :pep:`{title.replace('`', '')} <{number}>`")
         self.emit_text(f"     - {authors}")
         if python_version is not None:
-            self.emit_text(f"     - {python_version}")
+            pep_number = self.release_peps.get(python_version)
+
+            if pep_number is not None:
+                self.emit_text(
+                    f"     - :pep:`{python_version} <{pep_number}>`"
+                )
+            else:
+                self.emit_text(f"     - {python_version}")
 
     def emit_column_headers(self, *, include_version=True) -> None:
         """Output the column headers for the PEP indices."""
diff --git a/pep_sphinx_extensions/tests/pep_zero_generator/test_writer.py b/pep_sphinx_extensions/tests/pep_zero_generator/test_writer.py
index 3237dfb0562..4407f8f8224 100644
--- a/pep_sphinx_extensions/tests/pep_zero_generator/test_writer.py
+++ b/pep_sphinx_extensions/tests/pep_zero_generator/test_writer.py
@@ -86,3 +86,20 @@ def test_sort_authors():
 
     # Assert
     assert out == ["Aardvark, Alfred", "lowercase, laurence", "Zebra, Zoë"]
+
+
+def test_emit_pep_row_links_python_version_to_release_pep():
+    # Arrange
+    pep0_writer = writer.PEPZeroWriter(release_peps={"3.14": 745})
+
+    # Act
+    pep0_writer.emit_pep_row(
+        shorthand="Active",
+        number=999,
+        title="Test PEP",
+        authors="Test Author",
+        python_version="3.14",
+    )
+
+    # Assert
+    assert "     - :pep:`3.14 <745>`" in pep0_writer.output